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原文連結
論文資訊
- 類型：已發表論文
- 日期：2021-02-18
摘要
Structure-forming systems are ubiquitous in nature, ranging from atoms building molecules to self-assembly of colloidal amphibolic particles. The understanding of the underlying 熱力學s of such systems remains an important problem. Here, we derive the 熵 for structure-forming systems that differs from Boltzmann-Gibbs 熵 by a term that explicitly captures clustered states. For large systems and low concentrations the approach is equivalent to the grand-canonical ensemble; for small systems we find significant deviations. We derive the detailed fluctuation theorem and Crooks’ work fluctuation theorem for structure-forming systems. The connection to the theory of particle self-assembly is discussed. We apply the results to several physical systems. We present the phase diagram for patchy particles
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